Novel epothilone lactones by an unusual diversion of the Grubbs' metathesis reaction

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Novel epothilone lactones by an unusual diversion of the Grubbs' metathesis reaction.

An unusual reaction with Grubbs' catalyst during the synthesis of bridged epothilones yielded five-membered internal lactones instead of the expected metathesis products. Three of the lactones have activities comparable to epothilone D.

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ژورنال

عنوان ژورنال: Chemical Communications

سال: 2010

ISSN: 1359-7345,1364-548X

DOI: 10.1039/b926174e